You can create an application shortcut for the slingshotSlingshot (the applications menu) manually.
It should be placed toin /usr/share/applications/<APPNAME>.desktop
. Below is the way "SKype" shortcutSkype's .desktop file looks like. Copy the contents, replace with the data that will suit your application, and voila, it should appear in the menu:
$ cat /usr/share/applications/skype.desktop
[Desktop Entry]
Name=Skype
Comment=Skype Internet Telephony
Exec=env PULSE_LATENCY_MSEC=60 skype %U
Icon=skype.png
Terminal=false
Type=Application
Encoding=UTF-8
Categories=Network;Application;
MimeType=x-scheme-handler/skype;
X-KDE-Protocols=skype
Once it is in the menu -, you'll be able to pin it to the dock